It could focus on applications such as System Administration - simple scripts to make life easier (topics covered in Books such as Automate the boring Stuff with Python or Python for Informatics, by Chuck Severance). Data Science applications, simple Data mining and Web scraping for example. Topics like Information Security also spring to mind. There's a plethora of possible topics.
Also, of course, things like programming Raspberry Pi using Python could be integrated into the curriculum.
Adding a Python track would make this one-of-a-kind, awesome next-generation educational movement called Free Code Camp just even so much more awesome!
Let's get to it !